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Typical inspections of products from the WWT Process are summarized in Table 1. WWT plants can be designed to separate/recover a range of desired product quality - in fact, actual product inspections are generally better than those we quote as typical.

  Hydrogen
sulfide
Stripped
water
Anhydrous
ammonia
Form Gas Liquid Liquid
Ammonia, ppm < 100 < 50  
Hydrogen sulfide, ppm   < 10 < 5
Mercaptan sulfur, ppm     2-5
Water, wt. %     0.4
Temperature, °F (°C)     100 (38)
Pressure, psig (Bar)     200 (13.8)
Typical product inspections from the WWT process

Hydrogen sulfide

The hydrogen sulfide product will typically contain less than 100 ppm of ammonia, with only traces of hydrocarbons. Any carbon dioxide present in the sour water feed will remain in the hydrogen sulfide product.

The hydrogen sulfide is generally available at about 100 psig (6.9 Bar) and 100 ºF (38 ºC) and is saturated with water vapor.

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Waste water treatment unit
Waste water treatment unit

Stripped Water

The stripped water typically contains less than 50 ppm of free ammonia and less than 10 ppm of free hydrogen sulfide.

It also will contain traces of phenols and salts which entered with the feed.

Stripped water produced by the WWT Process may be reused or discharged through downstream treating facilities without problems. It has many reuse possibilities, including hydroprocessing unit injection water, crude unit desalter water and process water wash. For example, stripped water from WWT plants has been successfully reused in ISOCRACKING plants (the Chevron Lummus Global licensed hydrocracking process). WWT stripper water has been used successfully for many years as hydrocracker injection water.

The reuse of WWT water is particularly attractive because it reduces net makeup water requirements and can be an important step toward reducing waste water discharge rates to treating facilities and to receiving waters.

Ammonia

Ammonia produced as vapor for incineration will typically be scrubbed to reduce the hydrogen sulfide content to about 1500 ppm. The ammonia will be saturated with water at the scrubber temperature.

Under normal operating conditions, anhydrous liquid ammonia will have maximum free hydrogen sulfide and water contents of 5 ppmw and 0.4 Wt.%, respectively. Typical conditions at the plot limit are a temperature of 100ºF (38ºC) and a pressure of 200 psig (13.8 Bar). The anhydrous ammonia will contain trace amounts of mercaptans and oils.

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